Dartmouth College

Department of Chemistry

Russell P. Hughes Publications 2001-2005

135.    Russell P. Hughes, Danielle C. Lindner, Louise M. Liable-Sands, and Arnold L. Rheingold

           Conversion of Perfluorobenzyl Complexes of Rhodium to Fluorinated Oxorhodacycles.

           Organometallics2001, 20, 363.

 

136.    Russell P. Hughes, Susan M. Maddock, Ilia A. Guzei, Louise M. Liable-Sands, and Arnold L. Rheingold

           Reactions of Halofluorocarbons with Group 6 Complexes M(C5H5)2L (M = Mo, W; L = C2H4, CO).  Fluoroalkylation at Molybdenum and Tungsten, and at Cyclopentadienyl or Ethylene Ligands.

           J. Am. Chem. Soc., 2001, 123, 3279.

 

137.    Russell P. Hughes, Ivan Kovacik, Danielle C. Lindner, Jeremy M. Smith, Stefan Willemsen, Donghui

           Zhang, Ilia Guzei, and Arnold L. Rheingold.

           Unusual Reactivity of "Proton Sponge" as a Hydride Donor to Transition Metals: Synthesis and Structural Characterization of Fluoroalkyl(hydrido) Complexes of Iridium(III) and Rhodium(III).

           Organometallics., 2001, 20, 3190.

 

138.    Russell P. Hughes, Danielle C. Lindner, Jeremy M. Smith, Donghui Zhang, Christopher D. Incarvito, Kin-Chung Lam, Louise M. Liable-Sands, Roger D. Sommer, and Arnold L. Rheingold.

           Water, water, everywhere. Synthesis and Structures of Perfluoroalkyl Rhodium and Iridium(III) Compounds Containing Water Ligands.

           J. Chem. Soc. Dalton Trans.  2001, 2270.

 

139.    Russell P. Hughes, Joel T. Sweetser, Mark D. Tawa, Alex Williamson, Christopher D. Incarvito, Brian Rhatigan, Arnold L. Rheingold, and Gene Rossi

           Synthesis and Molecular Structures of Perfluoro-n-alkyl Complexes of Platinum(II) and Platinum(IV) Containing Tetramethylethylenediamine (TMEDA) or 1,2-Bis(diphenylphosphino)ethane (DPPE) Ligands.

           Organometallics. 2001, 20, 3800.

 

140.    Russell P. Hughes, Alex Williamson, Roger D. Sommer, and Arnold L. Rheingold

           The First Transition Metal Complex of Tetrafluorobenzyne: Ir(h5–C5Me5)(PMe3)(h2–C6F4).

           J. Am. Chem. Soc., 2001, 123, 7443.

 

141.    Russell P. Hughes, Alex Williamson, Christopher D. Incarvito, and Arnold L. Rheingold

           Synthesis and Molecular Structure of a Perfluoroalkyl Complex of Platinum Containing a PCP Pincer Ligand.

           Organometallics2001, 20, 4741.

 

142.    Russell P. Hughes, Trang Le Husebo, Susan M. Maddock, Louise M. Liable-Sands, and Arnold L. Rheingold

           Reactions of Perfluoro-iso-propyl Iodide with Cyclopentadienyl-Rhodium Complexes in Methanol.

           An Unexpected Route to a Rhodium–Fulvalene Complex.

           Organometallics, 2002, 21, 243.

 

143.    Russell P. Hughes, Jeremy M. Smith, Christopher D. Incarvito, Kin‑Chun Lam, Brian Rhatigan, and Arnold L. Rheingold

           Cationic Iridium‑Perfluoroalkyl Complexes with NH3 and PH3 Ligands.

           Activation of Carbon‑Fluorine Bonds by H2S to Give Bis(trifluoromethyl)dithiametallacyclobutane and Bis(trifluoromethyl)trithiametallacyclohexane Complexes.

           Organometallics2002, 21, 2136.

 

144.    Allen A. Bowden, Russell P. Hughes, Danielle C. Lindner, Christopher D. Incarvito, Louise M. Liable‑Sands, and Arnold L. Rheingold.

           Synthesis and Structural Studies of Perfluoroalkyl‑Rhodium and Iridium(III) Compounds Containing Tris(pyrazolyl)borate Ligands.

           J. Chem. Soc. Dalton Trans.  2002, 3245.

 

145.    Russell P. Hughes, Stefan Willemsen, Alex Williamson, and Donghui Zhang

           Carbon-Fluorine Bond Hydrogenolysis in Perfluoroethyl-Iridium Complexes to Give HFC-134a Involves Heterolytic Activation of H2.

           Organometallics, 2002, 21, 3085.

 

146.    Blair F. Johnston, David W. H. Rankin, Heather E. Robertson, Russell P. Hughes, and Jeffrey R. Lomprey

           The Molecular Structure of Ru(h-C5Me5)(h-C5F5) by Gas-Phase Electron Diffraction and Density Functional Theory.

           Organometallics, 2002, 21, 4840.

 

147.    Russell P. Hughes, Roman B. Laritchev, Alex Williamson, Christopher D. Incarvito, Lev N. Zakharov, and Arnold L. Rheingold

           Iridium and Rhodium Complexes Containing Fluorinated Phenyl Ligands and their Transformation to

           h2‑Benzyne Complexes, Including the Parent Benzyne Complex IrCp*(PMe3)(C6H4).

           Organometallics, 2002, 21, 4873.

 

148.    Russell P. Hughes, Donghui Zhang, Lev N. Zakharov, and Arnold L. Rheingold

           Selective Protonation at a C-F Bond in the Presence of an Iridium-Methyl Bond Gives Diastereoselective Carbon-Fluorine Bond Activation and Carbon-Carbon Bond Formation. A New Path to Carbon Stereocenters Bearing Fluorine Atoms

           Organometallics, 2002, 21, 4902.

 

149.    Russell P. Hughes, Jason S. Overby, Kin-Chung Lam, Christopher D. Incarvito, and Arnold L. Rheingold

           Oxidative Addition Reaction of Perfluoro‑n‑butyl Iodide to (COD)PtMe2 to give (COD)PtMe(nC4F9).

           The Molecular Structure of (COD)PtMe2.

           Polyhedron2002, 21, 2357.

 

150.    Russell P. Hughes, Roman B. Laritchev, Alex Williamson, Christopher D. Incarvito, Lev N. Zakharov, and Arnold L. Rheingold

           Reactions of Iridium and Rhodium Complexes Containing h2‑Benzyne, h2‑Tetrafluorobenzyne, and

           h2‑Trifluorobenzyne Ligands. Differential Rates of Arene Elimination by Protonation of Isomeric Fluoroaryl Complexes, and Restricted Rotation of PMe3 Ligands in ortho‑Iodo and ortho‑Bromoaryl Complexes.

           Organometallics2003, 22, 2134.

 

151.    Russell P. Hughes, Antony J. Ward, Arnold L. Rheingold, and Lev N. Zakaharov

           Synthesis and Molecular Structures of Platinum(II) and Platinum(IV) Diimine Complexes Possessing Fluoroalkyl Ligands.

           Can. J. Chem., 2003, 81, 1270.

 

152.    Russell P. Hughes, Monique A. Meyer, Mark D. Tawa, Antony J. Ward, Alex Williamson, Arnold L. Rheingold, and Lev N. Zakharov

           Does a‑Fluorination Affect the Structural trans‑Influence and Kinetic trans‑Effect of an Alkyl Ligand? Molecular Structures of Pd(TMEDA)(CH3)(RF) and a Kinetic Study of the trans to cis Isomerization of Pt(TMEDA)(CH3)2I(RF) [RF = CF2CF3, CFHCF3, CH2CF3]

           Inorg. Chem., 2004, 43, 747.

 

153.    Russell P. Hughes, Roman B. Laritchev. Lev N. Zakharov, and Arnold L. Rheingold

           Reductive Activation of Carbon-Fluorine Bonds in Fluoroalkyl Ligands: an Unexpected Route to the Only Known Tetrafluorobutatriene Transition Metal Complex, Ir(h5-C5Me5)(PMe3)(2,3-h2-CF2=C=C=CF2)

           J. Am. Chem. Soc., 2004, 126, 2308-2309.

 

154.    Russell P Hughes, Donghui Zhang, Antony J. Ward, Lev N. Zakharov, and Arnold L. Rheingold

           Conformational Analysis And Assignments of Relative Stereocenter Configurations in Fluoroalkyl-Iridium Complexes Using 19F{1H} HOESY Experiments. Comparison with Solid State X-ray Structural Results.

           J. Am. Chem. Soc., 2004, 126, 6169-6178.

 

155.    Russell P. Hughes, Antony J. Ward, James A. Golen, Christopher D. Incarvito, Arnold L. Rheingold and Lev N. Zakharov

           Synthesis, molecular structures, and chemistry of some new palladium(II) and platinum(II) complexes with pentafluorophenyl ligands

           Dalton Trans., 2004, 2720-2727.

 

156.    Russell P. Hughes, Roman B. Laritchev, Lev. N. Zakharov, and Arnold L. Rheingold

           Carbon-Fluorine Bond Activation Coupled with Carbon-Carbon Bond Formation at Iridium. Confirmation of Complete Kinetic Diastereoselectivity at the New Carbon Stereocenter by Intramolecular Trapping Using Vinyl as the Migrating Group.

           J. Am. Chem. Soc., 2005, 127, 6325-6334.

 

157.    Cheryl J. Bourgeois, Russell P. Hughes, Trang L. Husebo, Jeremy M. Smith, Ilia M. Guzei, Louise M. Liable-Sands, Lev N. Zakharov and Arnold L. Rheingold,

           Reactions of Perfluoroalkyl Iodides with M(C5H5)(CO)(PMe3) [M = Rh, Ir]; Evidence for Direct Fluoroalkylation at a CO Ligand,

           Organometallics, 2005, 24, 6431-6439.

 

158.    Shaun A. Garratt, Russell P. Hughes, Ivan Kovacik, Antony J. Ward, Stefan Willemsen and Donghui Zhang,

           Carbon-Fluorine Bond Activation Coupled with Carbon-Hydrogen Bond Formation a to Iridium:  Kinetics, Mechanism, and Diastereoselectivity,

           J. Am. Chem. Soc., 2005, 127, 15585-15594.

 

159.    Russell P. Hughes, Roman B. Laritchev, Jian Yuan, James A. Golen, Adam N. Rucker and Arnold L. Rheingold,

           A Simple Route to Difluorocarbene and Perfluoroalkylidene Complexes of Iridium,

           J. Am. Chem. Soc., 2005, 127, 15020-15021.

 

160.    Russell P. Hughes, Roman B. Laritchev, Lev N. Zakharov and Arnold L. Rheingold,

           Unexpected Formation of an Organoplatinum(IV) Fluoride Complex in the Reaction of Pt(TMEDA)(CH3)2 with Perfluoro-sec-butyl Iodide,

           Organometallics, 2005, 24, 4845-4848.