Dartmouth College

Department of Chemistry

Russell P. Hughes Publications 1996-2000

 

111.   R.P. Hughes, A. S. Kowalski, J. R. Lomprey, and D. R. Neithamer

          A New Synthesis of 1,5-Di-tert-butyl-1,3-cyclopentadiene by Dehydration of an Epoxide,

          and Characterization of its Diels-Alder Dimer.

          J. Org. Chem., 1996, 61, 401.

 

112.   R.P. Hughes and H. A. Trujillo

          Selective Solubility of Organometallic Complexes in Saturated Fluorocarbons.

          Synthesis of Cyclopentadienyl Ligands with Fluorinated Ponytails.

          Organometallics, 1996, 15, 286.

 

113.   R.P. Hughes, J. R. Lomprey, A. L. Rheingold, and G. P. A. Yap

          Molybdenum and Tungsten Complexes Containing the 1,2-Di-tert-Butylcyclopentadienyl Ligand.

          J. Organomet. Chem., 1996, 517, 63.

 

114.   R.P. Hughes, J. R. Lomprey, A. L. Rheingold, B. S. Haggerty, and G. P. A. Yap

          Synthesis and Molecular Structures of Titanocene, Zirconocene, and Uranocene Dichlorides

          Containing 1,2–Di–tert–Butylcyclopentadienyl Ligands.

          J. Organomet. Chem., 1996, 517, 89.

 

115.   R. P. Hughes, D. C. Lindner, A. L. Rheingold,  and G. P. A. Yap

          Perfluorobenzyl Complexes of Cobalt and Rhodium.

          Unusual Coupling Between Pentafluorophenyl and Pentamethylcyclopentadienyl Rings.

          Organometallics, 1996, 15, 5678.

 

116.   R. P. Hughes, T. L. Husebo, A. L. Rheingold, L. M. Liable-Sands, and G. P. A. Yap

          Ancillary Ligand Controlled Selectivity for Metal or Cyclopentadienyl Ring Fluoroalkylation in

          Reactions of Fluoroalkyl Iodides with Cyclopentadienyl–Rhodium Complexes.

          Organometallics, 1997, 16, 5.

 

117.   D. E. Richardson, L. Lang, J. R. Eyler, S. R. Kircus, X. Zheng, C. A.  Morse, and R. P. Hughes

          Additivity of Fluorine Substituent Effects in Ruthenocene Ionization Energetics.

          Organometallics, 1997, 16, 149.

 

118.   R. P. Hughes, D. C. Lindner, A. L. Rheingold,  and G. P. A. Yap

          Synthesis and Structure of the Thallium(I) Salt of the

          [Tetrakis{3,5-bis(trifluoromethyl)phenyl}borate] Anion

          Inorg. Chem., 1997, 36, 1726.

 

119.   R. P. Hughes, S. M. Maddock, A. L. Rheingold, and L. M. Liable-Sands

          Selective Fluoroalkylation of Cyclopentadienyl and Ethylene Ligands in Reactions of Perfluoroalkyl

          Iodides with Low Valent Complexes of Molybdenum and Tungsten;

          Evidence for a Fluorocarbanion Mechanism.

          J. Am. Chem. Soc., 1997, 119, 5988

 

120.   R. P. Hughes, T. L. Husebo, B. J. Holliday, A. L. Rheingold, and L. M. Liable-Sands

          Fluoroalkylation of Cobalt Complexes:

          Selective Reactions at the Metal or the Cyclopentadienyl Ring

          J. Organomet. Chem., 1997, 548, 109.

 

121.   R. P. Hughes, T. L. Husebo, S. M. Maddock, A. L. Rheingold, and I. A. Guzei

          Thallium(I) Selectively Abstracts Fluoride from a Tertiary Carbon–Fluorine Bond Under Conditions Where

          Silver(I) Selectively Abstracts Iodide from Rhodium.

          J. Am. Chem. Soc.1997, 119, 10231.

 

122.   R. P. Hughes, D. C. Lindner, A. L. Rheingold, and L. M. Liable-Sands

          Facile Activation of Carbon–Fluorine Bonds in Saturated Fluoroalkyl Ligands by Coordinated Water in

          Fluoroalkyl(Aqua) Complexes of Rhodium.

          J. Am. Chem. Soc.1997, 119, 11544.

 

123.   D. L. Lichtenberger, Y. Elkadi, N. E. Gruhn, R. P. Hughes, O.J. Curnow, and X. Zheng

          Electronic Structure Perturbations of Substituted Ruthenocenes:

          The First Photoelectron Spectra of Perchloro- and Perfluorocyclopentadienyl Complexes

          Organometallics1997, 16, 5209.

 

124.   R. P. Hughes and A. S. Kowalski

          Flash Vacuum Thermolysis of h5-Oxocyclohexadienyl Complexes of Ruthenium to Give

          h5-Cyclopentadienyl Ligands.

          Organometallics, 1998, 17, 270.

 

125.   R .P. Hughes, X. Zheng, C. A. Morse, O. J. Curnow,  J.  R. Lomprey, A. L. Rheingold,

          and G. P.A. Yap

          Syntheses of the Complete Set of Isomerically Pure, Partially Fluorinated Cyclopentadienyl Ligands

          (C5F5-nHn) [x = 1-4] by Flash Vacuum Thermolysis of h5-Oxocyclohexadienyl Ruthenium Complexes.

          Molecular Structures of [Ru(h5-C5Me5)(h5-C5-1,2-F2H3)] and [Ru(h5-C5Me5)(h5-C5H4F)]

          Organometallics, 1998, 17, 457.

 

126.   R. P. Hughes, S. M. Maddock, A. L. Rheingold, and I. A. Guzei

          Selective Conversion of an Ethylene to an Ethylidene Ligand in Reactions of a

          Hydrido(Ethylene) Complex of Tantalum with Iodofluorocarbons.

          Molecular Structure of [Ta(h5-C5H5)2(h1-CHCH3)I].

          Polyhedron, 1998, 17, 1037.

 

127.   V. Herrera, P. J. F. de Rege, I. T. Horváth, T. L. Husebo, and R. P. Hughes

          Tuning the Fluorous Partition Coefficients of Organometallic Complexes.

          The Synthesis and Characterization of [h5-C5H4CH2CH2(CF2)9CF3]Rh(CO)L (L = CO or P[CH2CH2(CF2)5CF3]3)

          and Cl2Ni{ P[CH2CH2(CF2)5CF3]3}2

          Inorg. Chem. Commun, 1998, 1, 197.

 

128.   R. P. Hughes and J. M. Smith

          Hydrogenolysis of Aliphatic Carbon–Fluorine Bonds in Fluoroalkyl-Iridium Complexes

          to Give Hydrofluorocarbons.

          J. Am. Chem. Soc., 1999, 121, 6084.

 

129.   R. P. Hughes,  H. A. Trujillo, J. W. Egan, Jr., and A. L. Rheingold

          Skeletal Rearrangement During Rhodium Promoted Ring Opening of

          1,2-Diphenyl-3-vinyl-1-cyclopropene. Preparation and Characterization of

          1,2- and 2,3-Diphenyl-3,4-Pentadienediyl Rhodium Complexes and their Ring Closure to a

          1,2-Diphenylcyclopentadienyl Complex.

          Organometallics, 1999, 18, 2766.

 

130.    R. P. Hughes

          Fluorine: Fascination, Frustration, Fulfillment.

          Fluorine Chemistry at the Millennium: Fascinated by Fluorine, Banks, R.E. (Ed), Elsevier, 2000, p. 618.

 

131.   R. P. Hughes,  H. A. Trujillo, J. W. Egan, Jr., and A. L. Rheingold

          Iridium Promoted Reactions of Carbon-Carbon Bonds. Skeletal Rearrangement of a Vinylcyclopropene

          During Iridacyclohexadiene Formation and Subsequent Isomerization of Iridacyclohexadienes

          via a,a'–Substituent Migrations.

          J. Am. Chem. Soc., 2000, 122, 2261.

 

132.   Russell P. Hughes, Jeremy M. Smith, Louise M. Liable-Sands, Thomas E. Concolino, Kin-Chung Lam,

          Christopher Incarvito and Arnold L. Rheingold.

          Syntheses and X-ray crystallographic studies of [Ir(h5-C5Me5)(L)(RF)I] (L = CO, PMe3;

          RF = CF2CF3, CF2CF2CF3, CF2C6F5, CF(CF3)2) complexes.

          Cone and solid angle steric parameters for perfluoroalkyl ligands.

          J.  Chem. Soc. Dalton Trans.  2000, 873.

 

133.   Mélanie D. Blanchard, Russell P. Hughes, Thomas Concolino, and Arnold L. Rheingold.

          p-Stacking Between Pentafluorophenyl and Phenyl Groups as a Controlling Feature of

          Intra- and Intermolecular Crystal Structure Motifs in Substituted Ferrocenes.

          Observation of Unexpected Face-to-Face Stacking between Pentafluorophenyl Rings.

          Chemistry of Materials2000, 12, 1604.

 

134.   Russell P. Hughes, Jason S. Overby, Alex Williamson, Kin-Chung Lam, Thomas E. Concolino,

          and Arnold L. Rheingold.

          Synthesis, Molecular Structures, and Dynamics of Primary and Secondary Fluoroalkyl Complexes

          of Palladium(II) with Tetramethylethylenediamine (TMEDA) Ligands.

          Evaluation of the Structural trans-Influences of Methyl and Fluoroalkyl Groups as Ligands

          Within the Same Coordination Sphere.

          Organometallics2000, 19, 5190.