Dartmouth College

Department of Chemistry

Russell P. Hughes Publications 1969-1975

1.          R.P. Hughes and J. Powell,

             The Reaction of Allene with Acetylacetonato-π-allylpalladium(II);

             Formation of 2,2'-Bi-π-allyl Complexes of Palladium(II),

             J. Organomet. Chem., 1969, 20 , P17.

 

2.          R.P. Hughes and J. Powell,

             The Interaction of Conjugated and Cumulated Dienes with Allylic Palladium Systems.

             The Nature of the Rate-Determining Step for Insertion Reactions,

             J. Chem. Soc. Chem. Commun., 1971, 275.

 

3.          R.P. Hughes and J. Powell,

             Cis-Addition of a Palladium-Carbon Bond to Coordinated Olefins,

             J. Organomet. Chem., 1971, 30 , C45.

 

4.          R.P. Hughes and J. Powell,

             Insertion of 1,2-Dienes into π-Homoallylic Complexes of Palladium(II),

             J. Organomet. Chem., 1972, 34 , C51.

 

5.          E.M. Ban, R.P. Hughes, and J. Powell,

             The Interaction of Olefins, 1,2-Dienes, and 1,3-Dienes with Allylic

             and Homoallylic Palladium Systems,

             Proc. XIVth Intern.Conf.Coord.Chem.(Toronto), 1972, 77.

 

6.          R.P. Hughes and J. Powell,

             Annual Surveys of Organometallic Chemistry: Nickel, Palladium, and Platinum,

             Organomet. Chem. Revs., 1972, 10 , 207.

 

7.          R.P. Hughes and J. Powell,

             Transition Metal Promoted Reactions of Unsaturated Hydrocarbons.

             Part I.  The Mechanism of 1,3-Diene Insertion into the Allyl-Palladium Bond,

             J. Am. Chem. Soc., 1972, 94 , 7723.

 

8.          D.G. Cooper, R.P. Hughes, and J. Powell,

             Studies of Carbon-13 Shielding Effects in Metal-Alkyl, Metal-Olefin, and Metal-Allyl Bonds,

             J. Am. Chem. Soc., 1972, 94 , 9244.

 

9.          R.P. Hughes and J. Powell,

             2,2'-Bi-π-Allyl Complexes of Palladium(II),

             J. Organomet. Chem., 1973, 54 , 345.

 

10.        R.P. Hughes and J. Powell,

             The Dynamic Stereochemistry of the Allylic Ligand in a µ-Allylic Complex of Platinum(II),

             J. Organomet. Chem., 1973, 55 , C45.

 

11.        R.P. Hughes and J. Powell,

             Transition Metal Promoted Reactions of Unsaturated Hydrocarbons.

             Part II. Insertion of Bicyclic Olefins into Allylic-Palladium and Platinum Bonds,

             J. Organomet. Chem., 1973, 60 , 387.

 

12.        R.P. Hughes and J. Powell,

             Transition Metal Promoted Reactions of Unsaturated Hydrocarbons.

             Part III. Insertion of 1,2-Dienes into Allylic-Palladium Bonds,

             J. Organomet. Chem., 1973, 60 , 409.

13.        R.P. Hughes and J. Powell,

             A ¹H and ¹³C NMR Investigation of the Bonding in Norbornenyl

             Complexes of Palladium(II) and Platinum(II),

             J. Organomet. Chem., 1973, 60 , 427.

 

14.        E.M. Ban, R.P. Hughes, and J. Powell,

             The Role of Electronic Effects in Determining the Thermodynamic Stabilities

             of Olefin Complexes of Palladium(II) and Platinum(II),

             J. Chem. Soc. Chem. Commun., 1973, 591.

 

15.        R.P. Hughes, T.R. Jack, and J. Powell,

             A Study of Trihapto-pentahapto Equilibria in Heptadienyl-Palladium(II) Complexes

             and the Possible Role of Such Complexes in Metal Complex Catalyzed

             1,4-Polymerizations of 1,3-Butadiene,

             J. Organomet. Chem., 1973, 63 , 451.

 

16.        E.M. Ban, R.P. Hughes, and J. Powell,

             Transition Metal Promoted Reactions of Unsaturated Hydrocarbons.

             Part IV. Reactions of Norbornenyl Complexes of Palladium(II) with

             Group V Donor Ligands, Olefins, 1,3-Dienes, and 1,2-Dienes,

             J. Organomet. Chem., 1974, 69 , 455.

 

17.        M. Green and R.P. Hughes,

             Transition Metal Complexes of Methylenecyclopropanes:

             Ring-Opening Reactions Promoted by Palladium(II),

             J. Chem. Soc. Chem. Commun., 1974, 686.

 

18.        M. Bottrill, R. Goddard, M. Green, R.P. Hughes, M.K. Lloyd, S.H.Taylor, and P. Woodward,

             Reaction of Trifluoroacetonitrile with π-Allylic Complexes of Iridium(I) and with

             Dicarbonyl(cyclopentadienyl)methyliron: the Molecular and Crystal Structure of

             Carbonyl(cyclopentadienyl)-1-[1-iminotrifluoroethyl)imino]trifluoroethyl-Nw-iron,

             J. Chem. Soc. Dalton Trans., 1975, 1150.

 

19.        M. Bottrill, R. Goddard, M. Green, R.P. Hughes, B. Lewis, M.K. Lloyd, and P. Woodward,

             Addition of Hexafluorobut-2-yne to Coordinated 1,3-Dienes; Crystal Structures of the Adducts

             [Ru(CO)2{P(OCH2)3CMe}(C6H8)(C4F6)2] and [Fe(CO)2{P(OCH2)3CMe}(C7H8)(C4F6)2],

             J. Chem. Soc. Chem. Commun., 1975, 253.

 

20.        M. Green, J.A.K. Howard, R.P. Hughes, S.C. Kellett, and P. Woodward,

             Methylenecyclopropane Complexes of Rhodium(I), Iridium(I), Platinum(0), and Platinum(II);

             the Crystal and Molecular Structure of  Acetylacetonatobis(methylenecyclopropane)rhodium(I),

             J. Chem. Soc. Dalton Trans., 1975, 2007.

 

21.        R. Davis, M. Green, and R.P. Hughes,

             The Stepwise Diels-Alder Addition of Hexafluorobut-2-yne to Coordinated 1,3-Dienes,

             J. Chem. Soc. Chem. Commun., 1975, 405.

 

22.        M. Green, R.P. Hughes, and A.J. Welch,

             Ring Opening of 2,3-Bis(hydroxymethyl)methylenecyclopropanes with Fe₂(CO)₉;

             the Molecular Structure of a 1,4-Diene Complex of Iron(0),

             Tricarbonyl-h⁴-[3-methylene-4-vinyldihydrofuran-2(3H)-one]iron,

             J. Chem. Soc. Chem. Commun., 1975, 487.

23.        M. Green and R.P. Hughes,

             Regiospecific Rearrangements of h²- and h⁴-1,4-Diene Complexes of Iron(0);

             The Mechanisms of Metal Promoted 1,3-Hydrogen Shifts,

             J. Chem. Soc. Chem. Commun., 1975, 619.

 

24.        M Green and R.P. Hughes,

             Reactions of Cyclopentadienyl Metal Carbonyl Anions with the

             1,2,3-Tri-t-butylcyclopropenium Cation; Electrophilic Attack at Peripheral Ligands,

             J. Chem. Soc. Chem. Commun., 1975, 862.