ChemLab: Techniques

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Analytical Balance

pH Meter: Analog

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Top-loading Balance

Techniques

Calorimetry

Centrifugation

Quantitative Transfer

Titration

Vacuum Filtration

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Calorimetry

Calorimetry is used to determine the heat released or absorbed in a chemical reaction. The calorimeters shown here can determine the heat of a solution reaction at constant (atmospheric) pressure. The calorimeter is a double styrofoam cup fitted with a plastic top in which there is a hole for a thermometer. (It's crude, but very effective!) Key techniques for obtaining accurate results are starting with a dry calorimeter, measuring solution volumes precisely, and determining change in temperature accurately.

Using a Calorimeter
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Solutions volumes should be carefully measured with a graduated cylinder. Add solution completely, to a dry calorimeter. Don't forget to add the spin bar each time!

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Set up the calorimeter with the thermometer (0° to 50°C, graduated every 0.1°C) supported from a stand so that the bulb does not touch the bottom of the cup. Note that the thermometer used for calorimetry differs from the less accurate one in your glassware drawer. Clamp the calorimeter so that it rests on the stirrer. Be careful not to turn on the heat or you will melt the styrofoam.

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The change in temperature is determined by measuring the initial temperature, T1, of the reactants, and the maximum temperature, T2, of the contents of the calorimeter during the exothermic reaction. Use a magnifying glass to measure temperature values precisely.


Interpolate between the divisions of the themometer and record temperatures to +/- 0.01 °C. See your lab manual for a discussion of how to determine accurately the change in temperature from your graph of temperature vs. time.

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